Engineering Chemistry
Instructions:
- The marks are indicated in the right-hand margin.
- There are NINE questions in this paper.
- Attempt FIVE questions in all.
- Question No. 1 is compulsory.
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The shape of the ammonia (NH₃) molecule according to VSEPR theory is?
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Which of the following metal carbonyls obeys the 18-electron rule?
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UV-Visible spectroscopy mainly involves transitions of
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The resonance frequency, in NMR spectroscopy depends mainly on
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The Nernst equation is used to determine
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Which electrolyte is used in a lead-acid battery?
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Temporary hardness of water is mainly due to
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Which process removes hardness by exchanging Ca²⁺ and Mg²⁺ ions with Na⁺ ions?
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Which polymer is an example of a thermoplastic?
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Silicones are classified as
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Discuss the Photoelectric Effect and Heisenberg's Uncertainty Principle with suitable examples.
[7] -
Describe the formation of Molecular Orbitals using the Linear Combination of Atomic Orbitals. Draw and explain the molecular orbital diagram of O₂.
[7]
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Explain the principles of rotational and vibrational spectroscopy and applications of these techniques in structural elucidation of organic molecule.
[7] -
Describe the principle, instrumentation, and applications of UV-Visible spectroscopy in chemistry.
[7]
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Derive the Nernst equation and explain its significance in determining the EMF of electrochemical cells under non-standard conditions.
[7] -
Explain the mechanism of corrosion. Discuss different types of corrosion with suitable examples.
[7]
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What is hardness of water? Explain the types of hardness and describe the estimation of hardness by the EDTA method.
[7] -
Discuss in details the Lime-Soda process for the removal of hardness of water.
[7]
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Differentiate between thermoplastics and thermosetting plastics. Discuss the preparation, properties and applications of commercially important thermoplastics such as Polyethylene, Polyvinyl Chloride and Polystyrene.
[7] -
Describe the preparation, properties and applications of Phenol-Formaldehyde resin (Bakelite).
[7]
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Explain the Diels–Alder cyclization reaction and epoxide ring-opening reaction and their applications in organic synthesis.
[7] -
Discuss the synthesis of aspirin from salicylic acid. Explain the reaction mechanism and significance of aspirin as an important pharmaceutical drug.
[7]
Chemical Shift in NMR spectroscopy.
[7]Working and advantages of fuel cells.
[7]
Bonding metal carbonyls
Boiler problems such as sludge formation, scale formation, priming and foaming
Oxidation-reduction reactions in organic chemistry
Mechanism of free radical polymerization reaction
